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| U | Internacional | - | Bahia - BA | 0:2 (0:1) | ||
| R | Bahia - BA | - | Internacional | 1:1 (0:1) | ||
| U: 28.08.2014 03:00 | R: 05.09.2014 03:00 | Winnaars: Bahia - BA | ||||
| U | Fluminense RJ | - | Goiás - GO | 2:1 (2:0) | ||
| R | Goiás - GO | - | Fluminense RJ | 1:0 (0:0) | ||
| U: 28.08.2014 23:00 | R: 04.09.2014 03:00 | Winnaars: Goiás - GO | ||||
| U | Criciúma - SC | - | São Paulo FC | 2:1 (2:1) | ||
| R | São Paulo FC | - | Criciúma - SC | 2:0 (2:0) | ||
| U: 29.08.2014 01:00 | R: 05.09.2014 01:00 | Winnaars: São Paulo FC | ||||
| U | Sport Recife - PE | - | Vitória - BA | 0:1 (0:1) | ||
| R | Vitória - BA | - | Sport Recife - PE | 2:1 (1:0) | ||
| U: 29.08.2014 03:00 | R: 04.09.2014 03:00 | Winnaars: Vitória - BA | ||||
| U | Gimnasia de La Plata | - | Estudiantes | 0:0 (0:0) | ||
| R | Estudiantes | - | Gimnasia de La Plata | 1:0 (0:0) | ||
| U: 03.09.2014 19:00 | R: 17.09.2014 00:00 | Winnaars: Estudiantes | ||||
| U | Godoy Cruz | - | River Plate | 0:1 (0:0) | ||
| R | River Plate | - | Godoy Cruz | 2:0 (2:0) | ||
| U: 04.09.2014 02:15 | R: 18.09.2014 02:15 | Winnaars: River Plate | ||||
| U | Rosario Central | - | Boca Juniors | 1:1 (0:1) | ||
| R | Boca Juniors | - | Rosario Central | 3:0 (1:0) | ||
| U: 05.09.2014 02:15 | R: 19.09.2014 02:15 | Winnaars: Boca Juniors | ||||
| U | Atlético Nacional | - | General Díaz | 0:2 (0:2) | ||
| R | General Díaz | - | Atlético Nacional | 1:3 (0:1) | ||
| U: 11.09.2014 02:15 | R: 26.09.2014 02:30 | Winnaars: Atlético Nacional | ||||
| U | Barcelona | - | Libertad | 1:0 (1:0) | ||
| R | Libertad | - | Barcelona | 2:0 (2:0) | ||
| U: 12.09.2014 02:15 | R: 18.09.2014 02:15 | Winnaars: Libertad | ||||
| U | Independiente del Valle | - | Cerro Porteño | 1:0 (0:0) | ||
| R | Cerro Porteño | - | Independiente del Valle | 3:0 (1:0) | ||
| U: 17.09.2014 00:00 | R: 24.09.2014 02:15 | Winnaars: Cerro Porteño | ||||
| U | Deportivo Capiatá | - | Caracas FC | 1:1 (1:0) | ||
| R | Caracas FC | - | Deportivo Capiatá | 1:3 (0:1) | ||
| U: 17.09.2014 02:15 | R: 25.09.2014 00:00 | Winnaars: Deportivo Capiatá | ||||
| U | Peñarol | - | Deportivo Cali | 2:2 (0:0) | ||
| R | Deportivo Cali | - | Peñarol | 0:1 (0:1) | ||
| U: 17.09.2014 02:30 | R: 25.09.2014 02:15 | Winnaars: Peñarol | ||||
| U | Huachipato | - | Universidad Catolica | 2:0 (1:0) | ||
| R | Universidad Catolica | - | Huachipato | 1:0 (1:0) | ||
| U: 17.09.2014 23:00 | R: 25.09.2014 00:00 | Winnaars: Huachipato | ||||
| U | Universitario de Sucre | - | Universidad Cesar Vallejo | 2:2 (0:0) | ||
| R | Universidad Cesar Vallejo | - | Universitario de Sucre | 3:0 (0:0) | ||
| U: 18.09.2014 00:00 | R: 24.09.2014 00:00 | Winnaars: Universidad Cesar Vallejo | ||||
| U | Emelec | - | River Plate | 2:1 (1:0) | ||
| R | River Plate | - | Emelec | 1:1 (1:1) | ||
| U: 19.09.2014 02:15 | R: 26.09.2014 02:15 | Winnaars: Emelec | ||||
