| 1. Ronde | 13.08.2023 | Villarreal CF | - | Real Betis | 1:2 | ||||
| 2. Ronde | 18.08.2023 | RCD Mallorca | - | Villarreal CF | 0:1 |  |
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| 3. Ronde | 27.08.2023 | Villarreal CF | - | FC Barcelona | 3:4 | ||||
| 4. Ronde | 01.09.2023 | Cádiz CF | - | Villarreal CF | 3:1 | ||||
| 5. Ronde | 17.09.2023 | Villarreal CF | - | UD Almería | 2:1 | |
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| 6. Ronde | 24.09.2023 | Rayo Vallecano | - | Villarreal CF | 1:1 | ||||
| 9. Ronde | 08.10.2023 | Villarreal CF | - | UD Las Palmas | 1:2 | |
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| 10. Ronde | 22.10.2023 | Villarreal CF | - | Deportivo Alavés | 1:1 | |
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| 11. Ronde | 30.10.2023 | Granada CF | - | Villarreal CF | 2:3 | |
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| 12. Ronde | 05.11.2023 | Villarreal CF | - | Athletic Bilbao | 2:3 | |
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| 13. Ronde | 12.11.2023 | Atlético Madrid | - | Villarreal CF | 3:1 | |
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| 14. Ronde | 26.11.2023 | Villarreal CF | - | CA Osasuna | 3:1 | ||||
| 15. Ronde | 03.12.2023 | Sevilla FC | - | Villarreal CF | 1:1 |
Spanje
