| 33. Ronde | 28.04.2021 | Athletic Club | - | Real Valladolid | 2:2 | ||||
| 34. Ronde | 02.05.2021 | Real Valladolid | - | Real Betis | 1:1 | ||||
| 35. Ronde | 09.05.2021 | Valencia CF | - | Real Valladolid | 3:0 | ||||
| 36. Ronde | 13.05.2021 | Real Valladolid | - | Villarreal CF | 0:2 |  |
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| 38. Ronde | 22.05.2021 | Real Valladolid | - | Atlético Madrid | 1:2 |
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