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| U | Argentinos Juniors | - | Fluminense RJ | 1:1 (1:0) | ||
| R | Fluminense RJ | - | Argentinos Juniors | 2:0 (0:0) | ||
| U: 02.08.2023 00:00 | R: 09.08.2023 00:00 | Winnaars: Fluminense RJ | ||||
| U | Bolívar | - | Athletico Paranaense | 3:1 (2:1) | ||
| R | Athletico Paranaense | - | Bolívar | 4:5 (1:0, 2:0) d.p. | ||
| U: 02.08.2023 02:00 | R: 09.08.2023 02:00 | Winnaars: Bolívar | ||||
| U | River Plate | - | Internacional | 2:1 (0:1) | ||
| R | Internacional | - | River Plate | 9:8 (0:0, 2:1) d.p. | ||
| U: 02.08.2023 02:00 | R: 09.08.2023 02:00 | Winnaars: Internacional | ||||
| U | Deportivo Pereira | - | Independiente del Valle | 1:0 (0:0) | ||
| R | Independiente del Valle | - | Deportivo Pereira | 1:1 (1:0) | ||
| U: 03.08.2023 02:00 | R: 10.08.2023 02:00 | Winnaars: Deportivo Pereira | ||||
| U | Nacional | - | Boca Juniors | 0:0 (0:0) | ||
| R | Boca Juniors | - | Nacional | 4:2 (1:1, 2:2) d.p. | ||
| U: 03.08.2023 02:00 | R: 10.08.2023 02:00 | Winnaars: Boca Juniors | ||||
| U | Atlético Mineiro | - | Palmeiras | 0:1 (0:1) | ||
| R | Palmeiras | - | Atlético Mineiro | 0:0 (0:0) | ||
| U: 03.08.2023 02:30 | R: 10.08.2023 02:30 | Winnaars: Palmeiras | ||||
| U | Atlético Nacional | - | Racing Club | 4:2 (1:0) | ||
| R | Racing Club | - | Atlético Nacional | 3:0 (1:0) | ||
| U: 04.08.2023 02:00 | R: 11.08.2023 02:00 | Winnaars: Racing Club | ||||
| U | Flamengo RJ | - | Club Olimpia | 1:0 (0:0) | ||
| R | Club Olimpia | - | Flamengo RJ | 3:1 (1:1) | ||
| U: 04.08.2023 02:00 | R: 11.08.2023 02:00 | Winnaars: Club Olimpia | ||||
