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| U | Lanús | - | CF Pachuca | 0:3 (0:1) | ||
| R | CF Pachuca | - | Lanús | 2:2 (0:0) | ||
| U: 18.10.2006 | R: 31.10.2006 | Winnaars: CF Pachuca | ||||
| U | Colo-Colo | - | Gimnasia de La Plata | 4:1 (1:1) | ||
| R | Gimnasia de La Plata | - | Colo-Colo | 0:2 (0:0) | ||
| U: 19.10.2006 | R: 26.10.2006 | Winnaars: Colo-Colo | ||||
| U | Nacional | - | Athletico Paranaense | 1:2 (0:0) | ||
| R | Athletico Paranaense | - | Nacional | 4:1 (2:0) | ||
| U: 19.10.2006 | R: 25.10.2006 | Winnaars: Athletico Paranaense | ||||
| U | San Lorenzo | - | Deportivo Toluca | 3:1 (1:0) | ||
| R | Deportivo Toluca | - | San Lorenzo | 2:0 (1:0) | ||
| U: 25.10.2006 | R: 01.11.2006 | Winnaars: Deportivo Toluca | ||||
