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| U | CE L'Hospitalet | - | FC Barcelona | 0:1 (0:1) | ||
| R | FC Barcelona | - | CE L'Hospitalet | 9:0 (5:0) | ||
| U: 09.11.2011 22:00 | R: 22.12.2011 22:00 | Winnaars: FC Barcelona | ||||
| U | Albacete | - | Atlético Madrid | 2:1 (1:0) | ||
| R | Atlético Madrid | - | Albacete | 0:1 (0:1) | ||
| U: 08.12.2011 20:00 | R: 21.12.2011 20:00 | Winnaars: Albacete | ||||
| U | Real Oviedo | - | Athletic Bilbao | 0:1 (0:1) | ||
| R | Athletic Bilbao | - | Real Oviedo | 1:0 (0:0) | ||
| U: 08.12.2011 22:00 | R: 21.12.2011 22:00 | Winnaars: Athletic Bilbao | ||||
| U | Cádiz CF | - | Valencia CF | 0:0 (0:0) | ||
| R | Valencia CF | - | Cádiz CF | 4:0 (3:0) | ||
| U: 13.12.2011 20:00 | R: 22.12.2011 20:00 | Winnaars: Valencia CF | ||||
| U | SD Ponferradina | - | Real Madrid | 0:2 (0:1) | ||
| R | Real Madrid | - | SD Ponferradina | 5:1 (2:0) | ||
| U: 13.12.2011 20:00 | R: 20.12.2011 20:00 | Winnaars: Real Madrid | ||||
| U | CD Mirandés | - | Villarreal CF | 1:1 (1:0) | ||
| R | Villarreal CF | - | CD Mirandés | 0:2 (0:0) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: CD Mirandés | ||||
| U | Real Sociedad | - | Granada CF | 4:1 (2:0) | ||
| R | Granada CF | - | Real Sociedad | 2:1 (1:0) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: Real Sociedad | ||||
| U | Getafe CF | - | Málaga CF | 0:1 (0:0) | ||
| R | Málaga CF | - | Getafe CF | 2:2 (1:0) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: Málaga CF | ||||
| U | RCD Mallorca | - | Sporting Gijón | 0:1 (0:0) | ||
| R | Sporting Gijón | - | RCD Mallorca | 0:2 (0:1) | ||
| U: 13.12.2011 21:00 | R: 20.12.2011 20:00 | Winnaars: RCD Mallorca | ||||
| U | Deportivo La Coruña | - | Levante UD | 3:1 (2:0) | ||
| R | Levante UD | - | Deportivo La Coruña | 4:1 (2:1, 3:1) n.v. | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: Levante UD | ||||
| U | Córdoba CF | - | Real Betis | 1:0 (0:0) | ||
| R | Real Betis | - | Córdoba CF | 2:1 (1:1) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: Córdoba CF | ||||
| U | AD Alcorcón | - | Real Zaragoza | 1:1 (1:1) | ||
| R | Real Zaragoza | - | AD Alcorcón | 0:2 (0:0) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: AD Alcorcón | ||||
| U | UD Almería | - | CA Osasuna | 1:3 (0:3) | ||
| R | CA Osasuna | - | UD Almería | 1:1 (0:0) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: CA Osasuna | ||||
| U | Celta de Vigo | - | Espanyol | 0:0 (0:0) | ||
| R | Espanyol | - | Celta de Vigo | 4:2 (1:0) | ||
| U: 13.12.2011 21:00 | R: 20.12.2011 20:00 | Winnaars: Espanyol | ||||
| U | Racing Santander | - | Rayo Vallecano | 3:2 (1:1) | ||
| R | Rayo Vallecano | - | Racing Santander | 4:3 (3:1) | ||
| U: 13.12.2011 21:00 | R: 21.12.2011 21:00 | Winnaars: Racing Santander | ||||
| U | CD San Roque | - | Sevilla FC | 0:1 (0:1) | ||
| R | Sevilla FC | - | CD San Roque | 2:1 (0:0) | ||
| U: 13.12.2011 22:00 | R: 20.12.2011 22:00 | Winnaars: Sevilla FC | ||||
