| 6. Ronde | 17.09.2022 | Athletic Club | - | Rayo Vallecano | 3:2 | ||||
| 7. Ronde | 30.09.2022 | Athletic Club | - | UD Almería | 4:0 | ||||
| 8. Ronde | 08.10.2022 | Sevilla FC | - | Athletic Club | 1:1 |  |
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| 10. Ronde | 18.10.2022 | Getafe CF | - | Athletic Club | 2:2 |  |
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| 11. Ronde | 23.10.2022 | FC Barcelona | - | Athletic Club | 4:0 | ||||
| 14. Ronde | 08.11.2022 | Athletic Club | - | Real Valladolid | 3:0 | |
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| 18. Ronde | 22.01.2023 | Athletic Club | - | Real Madrid | 0:2 | |
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| 19. Ronde | 29.01.2023 | Celta de Vigo | - | Athletic Club | 1:0 | ||||
| 28. Ronde | 08.04.2023 | Espanyol | - | Athletic Club | 1:2 | ||||
| 29. Ronde | 15.04.2023 | Athletic Club | - | Real Sociedad | 2:0 | ||||
| 30. Ronde | 22.04.2023 | UD Almería | - | Athletic Club | 1:2 | ||||
| 31. Ronde | 27.04.2023 | Athletic Club | - | Sevilla FC | 0:1 | ||||
| 32. Ronde | 01.05.2023 | RCD Mallorca | - | Athletic Club | 1:1 | ||||
| 33. Ronde | 04.05.2023 | Athletic Club | - | Real Betis | 0:1 | ||||
| 34. Ronde | 13.05.2023 | Villarreal CF | - | Athletic Club | 5:1 | |
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| 35. Ronde | 20.05.2023 | Athletic Club | - | Celta de Vigo | 2:1 | ||||
| 38. Ronde | 04.06.2023 | Real Madrid | - | Athletic Club | 1:1 |
Spanje
