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| U | Sporting Gijón | - | FC Barcelona | 0:3 (0:3) | ||
| R | FC Barcelona | - | Sporting Gijón | 1:1 (1:1) | ||
| U: 04.01.1994 20:30 | R: 12.01.1994 20:45 | Winnaars: FC Barcelona | ||||
| U | Real Madrid | - | Atlético Madrid | 2:2 (1:1) | ||
| R | Atlético Madrid | - | Real Madrid | 2:3 (1:1) | ||
| U: 04.01.1994 21:00 | R: 13.01.1994 21:30 | Winnaars: Real Madrid | ||||
| U | Deportivo La Coruña | - | Real Oviedo | 1:3 (0:3) | ||
| R | Real Oviedo | - | Deportivo La Coruña | 0:1 (0:1) | ||
| U: 05.01.1994 20:30 | R: 12.01.1994 20:15 | Winnaars: Real Oviedo | ||||
| U | Espanyol | - | Sevilla FC | 0:1 (0:0) | ||
| R | Sevilla FC | - | Espanyol | 2:2 (1:1) | ||
| U: 05.01.1994 20:45 | R: 12.01.1994 21:00 | Winnaars: Sevilla FC | ||||
| U | CD Logroñés | - | Celta de Vigo | 1:0 (1:0) | ||
| R | Celta de Vigo | - | CD Logroñés | 4:3 (1:0, 1:0, 1:0) d.p. | ||
| U: 05.01.1994 21:00 | R: 12.01.1994 21:00 | Winnaars: Celta de Vigo | ||||
| U | CD Tenerife | - | Valencia CF | 3:1 (2:0) | ||
| R | Valencia CF | - | CD Tenerife | 3:2 (2:0) | ||
| U: 05.01.1994 22:00 | R: 12.01.1994 21:00 | Winnaars: CD Tenerife | ||||
| U | Real Betis | - | CP Mérida | 3:1 (1:0) | ||
| R | CP Mérida | - | Real Betis | 1:1 (0:0) | ||
| U: 06.01.1994 17:00 | R: 12.01.1994 21:00 | Winnaars: Real Betis | ||||
| U | CD Badajoz | - | Real Zaragoza | 1:0 (1:0) | ||
| R | Real Zaragoza | - | CD Badajoz | 3:0 (2:0) | ||
| U: 06.01.1994 17:00 | R: 12.01.1994 20:45 | Winnaars: Real Zaragoza | ||||
