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| U | Athletic Bilbao | - | Real Valladolid | 3:2 (1:1) | ||
| R | Real Valladolid | - | Athletic Bilbao | 0:1 (0:0) | ||
| U: 25.01.2005 21:00 | R: 03.02.2005 20:00 | Winnaars: Athletic Bilbao | ||||
| U | Sevilla FC | - | CA Osasuna | 2:1 (1:1) | ||
| R | CA Osasuna | - | Sevilla FC | 3:1 (1:0) | ||
| U: 26.01.2005 21:00 | R: 02.02.2005 20:00 | Winnaars: CA Osasuna | ||||
| U | UDA Gramenet | - | Real Betis | 2:2 (1:1) | ||
| R | Real Betis | - | UDA Gramenet | 4:3 (2:0) | ||
| U: 27.01.2005 21:00 | R: 02.02.2005 21:00 | Winnaars: Real Betis | ||||
| U | CD Numancia | - | Atlético Madrid | 0:0 (0:0) | ||
| R | Atlético Madrid | - | CD Numancia | 1:0 (0:0) | ||
| U: 02.02.2005 20:00 | R: 16.02.2005 21:00 | Winnaars: Atlético Madrid | ||||
