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| U | Atlético Madrid | - | CA Osasuna | 1:1 (0:1) | ||
| R | CA Osasuna | - | Atlético Madrid | 2:0 (2:0) | ||
| U: 09.01.2007 21:00 | R: 17.01.2007 21:00 | Winnaars: CA Osasuna | ||||
| U | Málaga CF | - | Real Zaragoza | 0:3 (0:1) | ||
| R | Real Zaragoza | - | Málaga CF | 0:1 (0:1) | ||
| U: 10.01.2007 20:00 | R: 17.01.2007 21:00 | Winnaars: Real Zaragoza | ||||
| U | Real Valladolid | - | Villarreal CF | 2:1 (1:1) | ||
| R | Villarreal CF | - | Real Valladolid | 0:1 (0:1) | ||
| U: 10.01.2007 20:00 | R: 17.01.2007 21:00 | Winnaars: Real Valladolid | ||||
| U | Rayo Vallecano | - | Sevilla FC | 0:0 (0:0) | ||
| R | Sevilla FC | - | Rayo Vallecano | 3:1 (1:1) | ||
| U: 10.01.2007 20:00 | R: 17.01.2007 21:00 | Winnaars: Sevilla FC | ||||
| U | RCD Mallorca | - | Deportivo La Coruña | 1:2 (0:0) | ||
| R | Deportivo La Coruña | - | RCD Mallorca | 1:1 (0:1) | ||
| U: 10.01.2007 20:00 | R: 17.01.2007 21:00 | Winnaars: Deportivo La Coruña | ||||
| U | Getafe CF | - | Valencia CF | 1:1 (1:0) | ||
| R | Valencia CF | - | Getafe CF | 2:4 (1:1) | ||
| U: 10.01.2007 21:30 | R: 17.01.2007 21:30 | Winnaars: Getafe CF | ||||
| U | Deportivo Alavés | - | FC Barcelona | 0:2 (0:0) | ||
| R | FC Barcelona | - | Deportivo Alavés | 3:2 (2:2) | ||
| U: 10.01.2007 21:30 | R: 16.01.2007 21:00 | Winnaars: FC Barcelona | ||||
| U | Real Betis | - | Real Madrid | 0:0 (0:0) | ||
| R | Real Madrid | - | Real Betis | 1:1 (1:1) | ||
| U: 11.01.2007 21:00 | R: 18.01.2007 21:00 | Winnaars: Real Betis | ||||
