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| U | Villarreal CF | - | Sevilla FC | 3:3 (2:1) | ||
| R | Sevilla FC | - | Villarreal CF | 3:0 (1:0) | ||
| U: 12.01.2011 20:00 | R: 18.01.2011 22:00 | Winnaars: Sevilla FC | ||||
| U | FC Barcelona | - | Real Betis | 5:0 (1:0) | ||
| R | Real Betis | - | FC Barcelona | 3:1 (3:1) | ||
| U: 12.01.2011 22:00 | R: 19.01.2011 22:00 | Winnaars: FC Barcelona | ||||
| U | UD Almería | - | Deportivo La Coruña | 1:0 (1:0) | ||
| R | Deportivo La Coruña | - | UD Almería | 2:3 (1:2) | ||
| U: 13.01.2011 20:00 | R: 19.01.2011 20:00 | Winnaars: UD Almería | ||||
| U | Real Madrid | - | Atlético Madrid | 3:1 (1:1) | ||
| R | Atlético Madrid | - | Real Madrid | 0:1 (0:1) | ||
| U: 13.01.2011 22:00 | R: 20.01.2011 22:00 | Winnaars: Real Madrid | ||||
