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| U | Real Madrid | - | Valencia CF | 2:0 (1:0) | ||
| R | Valencia CF | - | Real Madrid | 1:1 (0:1) | ||
| U: 15.01.2013 21:00 | R: 23.01.2013 21:30 | Winnaars: Real Madrid | ||||
| U | Real Zaragoza | - | Sevilla FC | 0:0 (0:0) | ||
| R | Sevilla FC | - | Real Zaragoza | 4:0 (2:0) | ||
| U: 16.01.2013 19:30 | R: 23.01.2013 19:30 | Winnaars: Sevilla FC | ||||
| U | FC Barcelona | - | Málaga CF | 2:2 (2:1) | ||
| R | Málaga CF | - | FC Barcelona | 2:4 (1:1) | ||
| U: 16.01.2013 21:30 | R: 24.01.2013 22:00 | Winnaars: FC Barcelona | ||||
| U | Atlético Madrid | - | Real Betis | 2:0 (2:0) | ||
| R | Real Betis | - | Atlético Madrid | 1:1 (0:1) | ||
| U: 17.01.2013 22:00 | R: 24.01.2013 20:00 | Winnaars: Atlético Madrid | ||||
