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| U | Espanyol | - | Real Madrid | 0:1 (0:1) | ||
| R | Real Madrid | - | Espanyol | 1:0 (1:0) | ||
| U: 21.01.2014 21:00 | R: 28.01.2014 21:00 | Winnaars: Real Madrid | ||||
| U | Real Sociedad | - | Racing Santander | 3:1 (2:0) | ||
| R | Racing Santander | - | Real Sociedad | 0:3 Toeg. | ||
| U: 22.01.2014 20:00 | R: 30.01.2014 | Winnaars: Real Sociedad | ||||
| U | Levante UD | - | FC Barcelona | 1:4 (1:0) | ||
| R | FC Barcelona | - | Levante UD | 5:1 (2:1) | ||
| U: 22.01.2014 22:00 | R: 29.01.2014 22:00 | Winnaars: FC Barcelona | ||||
| U | Atlético Madrid | - | Athletic Bilbao | 1:0 (1:0) | ||
| R | Athletic Bilbao | - | Atlético Madrid | 1:2 (1:0) | ||
| U: 23.01.2014 21:00 | R: 29.01.2014 20:00 | Winnaars: Atlético Madrid | ||||
