| 4. Ronde | 30.09.2020 | Real Madrid | - | Real Valladolid | 1:0 | ||||
| 20. Ronde | 23.01.2021 | Deportivo Alavés | - | Real Madrid | 1:4 | ||||
| 21. Ronde | 30.01.2021 | Real Madrid | - | Levante UD | 1:2 | ||||
| 22. Ronde | 06.02.2021 | SD Huesca | - | Real Madrid | 1:2 | ||||
| 30. Ronde | 10.04.2021 | Real Madrid | - | FC Barcelona | 2:1 | ||||
| 33. Ronde | 18.04.2021 | Getafe CF | - | Real Madrid | 0:0 | ||||
| 31. Ronde | 21.04.2021 | Cádiz CF | - | Real Madrid | 0:3 |  |
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| 32. Ronde | 24.04.2021 | Real Madrid | - | Real Betis | 0:0 | ||||
| 34. Ronde | 01.05.2021 | Real Madrid | - | CA Osasuna | 2:0 | ||||
| 35. Ronde | 09.05.2021 | Real Madrid | - | Sevilla FC | 2:2 | ||||
| 36. Ronde | 13.05.2021 | Granada CF | - | Real Madrid | 1:4 | |
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| 37. Ronde | 16.05.2021 | Athletic Club | - | Real Madrid | 0:1 | ||||
| 38. Ronde | 22.05.2021 | Real Madrid | - | Villarreal CF | 2:1 |
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