| 1. Ronde | 13.08.2022 | FC Barcelona | - | Rayo Vallecano | 0:0 | ||||
| 2. Ronde | 21.08.2022 | Real Sociedad | - | FC Barcelona | 1:4 |  |
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| 3. Ronde | 28.08.2022 | FC Barcelona | - | Real Valladolid | 4:0 | |
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| 4. Ronde | 03.09.2022 | Sevilla FC | - | FC Barcelona | 0:3 | |
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| 5. Ronde | 10.09.2022 | Cádiz CF | - | FC Barcelona | 0:4 | |
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| 6. Ronde | 17.09.2022 | FC Barcelona | - | Elche CF | 3:0 | |
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| 7. Ronde | 01.10.2022 | RCD Mallorca | - | FC Barcelona | 0:1 | |
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| 8. Ronde | 09.10.2022 | FC Barcelona | - | Celta de Vigo | 1:0 | ||||
| 9. Ronde | 16.10.2022 | Real Madrid | - | FC Barcelona | 3:1 | ||||
| 10. Ronde | 20.10.2022 | FC Barcelona | - | Villarreal CF | 3:0 | |
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| 11. Ronde | 23.10.2022 | FC Barcelona | - | Athletic Bilbao | 4:0 | |
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| 12. Ronde | 29.10.2022 | Valencia CF | - | FC Barcelona | 0:1 | |
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| 13. Ronde | 05.11.2022 | FC Barcelona | - | UD Almería | 2:0 | ||||
| 14. Ronde | 08.11.2022 | CA Osasuna | - | FC Barcelona | 1:2 |  |
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| 15. Ronde | 31.12.2022 | FC Barcelona | - | Espanyol | 1:1 |
Polen
