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| U | Albacete | - | Athletic Bilbao | 0:0 (0:0) | ||
| R | Athletic Bilbao | - | Albacete | 4:0 (1:0) | ||
| U: 03.01.2012 20:00 | R: 12.01.2012 20:00 | Winnaars: Athletic Bilbao | ||||
| U | CD Mirandés | - | Racing Santander | 2:0 (1:0) | ||
| R | Racing Santander | - | CD Mirandés | 1:1 (1:0) | ||
| U: 03.01.2012 21:00 | R: 10.01.2012 21:00 | Winnaars: CD Mirandés | ||||
| U | AD Alcorcón | - | Levante UD | 2:1 (1:1) | ||
| R | Levante UD | - | AD Alcorcón | 4:0 (2:0) | ||
| U: 03.01.2012 21:00 | R: 11.01.2012 20:00 | Winnaars: Levante UD | ||||
| U | Real Madrid | - | Málaga CF | 3:2 (0:2) | ||
| R | Málaga CF | - | Real Madrid | 0:1 (0:0) | ||
| U: 03.01.2012 22:00 | R: 10.01.2012 22:00 | Winnaars: Real Madrid | ||||
| U | Real Sociedad | - | RCD Mallorca | 2:0 (1:0) | ||
| R | RCD Mallorca | - | Real Sociedad | 6:1 (4:1) | ||
| U: 04.01.2012 20:00 | R: 10.01.2012 20:00 | Winnaars: RCD Mallorca | ||||
| U | FC Barcelona | - | CA Osasuna | 4:0 (2:0) | ||
| R | CA Osasuna | - | FC Barcelona | 1:2 (1:0) | ||
| U: 04.01.2012 22:00 | R: 12.01.2012 22:00 | Winnaars: FC Barcelona | ||||
| U | Córdoba CF | - | Espanyol | 2:1 (0:1) | ||
| R | Espanyol | - | Córdoba CF | 4:2 (3:1) | ||
| U: 05.01.2012 20:00 | R: 11.01.2012 21:00 | Winnaars: Espanyol | ||||
| U | Valencia CF | - | Sevilla FC | 1:0 (1:0) | ||
| R | Sevilla FC | - | Valencia CF | 2:1 (0:0) | ||
| U: 05.01.2012 22:00 | R: 11.01.2012 22:00 | Winnaars: Valencia CF | ||||
