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| 18.09.1966 | CD Logroñés | - | Real Valladolid | 1:0 | ||
| CD Tenerife | - | Sporting Gijón | 1:1 | |||
| Racing Ferrol | - | Burgos CF | 4:0 | |||
| Real Oviedo | - | Rayo Vallecano | 0:1 | |||
| Gimnástica Torrelavega | - | Racing Santander | 2:1 | |||
| SD Indautxu | - | CF Calvo Sotelo | 0:0 | |||
| UP Langreo | - | CA Osasuna | 2:1 | |||
| Real Sociedad | - | Celta de Vigo | 2:0 | |||
| Real Betis | - | CD Condal | 3:0 | |||
| UE Lleida | - | CF Badalona | 2:0 | |||
| Cádiz CF | - | Algeciras CF | 1:1 | |||
| CD Málaga | - | Recreativo Huelva | 2:1 | |||
| CD Mestalla | - | Real Murcia | 4:3 | |||
| CE Europa | - | RCD Mallorca | 1:0 | |||
| CA Ceuta | - | Levante UD | 2:0 | |||
| CD Constància | - | CD Castellón | 0:1 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Rayo Vallecano | 2 | 2 | 0 | 0 | 3:0 | 3 | 4:0 |
| 2 |
|
UP Langreo | 2 | 2 | 0 | 0 | 3:1 | 2 | 4:0 |
| 3 |
|
CF Calvo Sotelo | 2 | 1 | 1 | 0 | 4:0 | 4 | 3:1 |
| 4 |
|
Sporting Gijón | 2 | 1 | 1 | 0 | 2:1 | 1 | 3:1 |
| 5 |
|
Racing Santander | 2 | 1 | 0 | 1 | 5:2 | 3 | 2:2 |
| 6 |
|
Racing Ferrol | 2 | 1 | 0 | 1 | 4:1 | 3 | 2:2 |
| 7 |
|
Celta de Vigo | 2 | 1 | 0 | 1 | 2:2 | 0 | 2:2 |
| 8 |
|
CD Logroñés | 2 | 1 | 0 | 1 | 1:2 | -1 | 2:2 |
| 9 |
|
Real Sociedad | 2 | 1 | 0 | 1 | 2:4 | -2 | 2:2 |
| 10 |
|
CA Osasuna | 2 | 1 | 0 | 1 | 4:2 | 2 | 2:2 |
| 11 |
|
Real Oviedo | 2 | 1 | 0 | 1 | 2:2 | 0 | 2:2 |
| 12 |
|
Gimnástica Torrelavega | 2 | 1 | 0 | 1 | 2:5 | -3 | 2:2 |
| 13 |
|
SD Indautxu | 2 | 0 | 1 | 1 | 0:3 | -3 | 1:3 |
| 14 |
|
CD Tenerife | 2 | 0 | 1 | 1 | 1:3 | -2 | 1:3 |
| 15 |
|
Real Valladolid | 2 | 0 | 0 | 2 | 1:3 | -2 | 0:4 |
| 16 |
|
Burgos CF | 2 | 0 | 0 | 2 | 0:5 | -5 | 0:4 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Betis | 2 | 1 | 1 | 0 | 4:1 | 3 | 3:1 |
| 2 |
|
CD Castellón | 2 | 1 | 1 | 0 | 2:1 | 1 | 3:1 |
|
CD Málaga | 2 | 1 | 1 | 0 | 2:1 | 1 | 3:1 | |
| 4 |
|
CE Europa | 2 | 1 | 1 | 0 | 2:1 | 1 | 3:1 |
| 5 |
|
UE Lleida | 2 | 1 | 0 | 1 | 2:1 | 1 | 2:2 |
| 6 |
|
CD Condal | 2 | 1 | 0 | 1 | 4:4 | 0 | 2:2 |
| 7 |
|
Algeciras CF | 2 | 0 | 2 | 0 | 2:2 | 0 | 2:2 |
|
Recreativo Huelva | 2 | 1 | 0 | 1 | 2:2 | 0 | 2:2 | |
| 9 |
|
CA Ceuta | 2 | 1 | 0 | 1 | 2:3 | -1 | 2:2 |
| 10 |
|
CF Badalona | 2 | 1 | 0 | 1 | 1:2 | -1 | 2:2 |
|
Levante UD | 2 | 1 | 0 | 1 | 1:2 | -1 | 2:2 | |
| 12 |
|
CD Mestalla | 2 | 1 | 0 | 1 | 5:7 | -2 | 2:2 |
| 13 |
|
Real Murcia | 2 | 1 | 0 | 1 | 6:4 | 2 | 2:2 |
| 14 |
|
Cádiz CF | 2 | 0 | 1 | 1 | 1:2 | -1 | 1:3 |
| 15 |
|
RCD Mallorca | 2 | 0 | 1 | 1 | 0:1 | -1 | 1:3 |
| 16 |
|
CD Constància | 2 | 0 | 0 | 2 | 0:2 | -2 | 0:4 |
