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| 25.09.1966 | Racing Santander | - | SD Indautxu | 2:0 | ||
| Real Valladolid | - | Real Sociedad | 3:1 | |||
| Rayo Vallecano | - | CD Logroñés | 8:0 | |||
| CA Osasuna | - | Racing Ferrol | 1:5 | |||
| Real Oviedo | - | CD Tenerife | 3:1 | |||
| Celta de Vigo | - | Gimnástica Torrelavega | 4:2 | |||
| Burgos CF | - | Sporting Gijón | 0:2 | |||
| CF Calvo Sotelo | - | UP Langreo | 1:0 | |||
| CD Castellón | - | UE Lleida | 1:0 | |||
| RCD Mallorca | - | Cádiz CF | 3:0 | |||
| Real Murcia | - | Real Betis | 1:2 | |||
| Recreativo Huelva | - | CE Europa | 1:0 | |||
| Algeciras CF | - | Levante UD | 1:2 | |||
| CD Mestalla | - | CA Ceuta | 2:2 | |||
| CF Badalona | - | CD Málaga | 1:1 | |||
| CD Condal | - | CD Constància | 1:2 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Rayo Vallecano | 3 | 3 | 0 | 0 | 11:0 | 11 | 6:0 |
| 2 |
|
CF Calvo Sotelo | 3 | 2 | 1 | 0 | 5:0 | 5 | 5:1 |
| 3 |
|
Sporting Gijón | 3 | 2 | 1 | 0 | 4:1 | 3 | 5:1 |
| 4 |
|
Racing Ferrol | 3 | 2 | 0 | 1 | 9:2 | 7 | 4:2 |
| 5 |
|
Racing Santander | 3 | 2 | 0 | 1 | 7:2 | 5 | 4:2 |
| 6 |
|
Celta de Vigo | 3 | 2 | 0 | 1 | 6:4 | 2 | 4:2 |
| 7 |
|
UP Langreo | 3 | 2 | 0 | 1 | 3:2 | 1 | 4:2 |
| 8 |
|
Real Oviedo | 3 | 2 | 0 | 1 | 5:3 | 2 | 4:2 |
| 9 |
|
Real Valladolid | 3 | 1 | 0 | 2 | 4:4 | 0 | 2:4 |
| 10 |
|
Real Sociedad | 3 | 1 | 0 | 2 | 3:7 | -4 | 2:4 |
| 11 |
|
CD Logroñés | 3 | 1 | 0 | 2 | 1:10 | -9 | 2:4 |
| 12 |
|
CA Osasuna | 3 | 1 | 0 | 2 | 5:7 | -2 | 2:4 |
| 13 |
|
Gimnástica Torrelavega | 3 | 1 | 0 | 2 | 4:9 | -5 | 2:4 |
| 14 |
|
SD Indautxu | 3 | 0 | 1 | 2 | 0:5 | -5 | 1:5 |
| 15 |
|
CD Tenerife | 3 | 0 | 1 | 2 | 2:6 | -4 | 1:5 |
| 16 |
|
Burgos CF | 3 | 0 | 0 | 3 | 0:7 | -7 | 0:6 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Betis | 3 | 2 | 1 | 0 | 6:2 | 4 | 5:1 |
| 2 |
|
CD Castellón | 3 | 2 | 1 | 0 | 3:1 | 2 | 5:1 |
| 3 |
|
CD Málaga | 3 | 1 | 2 | 0 | 3:2 | 1 | 4:2 |
|
Recreativo Huelva | 3 | 2 | 0 | 1 | 3:2 | 1 | 4:2 | |
| 5 |
|
Levante UD | 3 | 2 | 0 | 1 | 3:3 | 0 | 4:2 |
| 6 |
|
RCD Mallorca | 3 | 1 | 1 | 1 | 3:1 | 2 | 3:3 |
| 7 |
|
CA Ceuta | 3 | 1 | 1 | 1 | 4:5 | -1 | 3:3 |
| 8 |
|
CF Badalona | 3 | 1 | 1 | 1 | 2:3 | -1 | 3:3 |
| 9 |
|
CD Mestalla | 3 | 1 | 1 | 1 | 7:9 | -2 | 3:3 |
| 10 |
|
CE Europa | 3 | 1 | 1 | 1 | 2:2 | 0 | 3:3 |
| 11 |
|
UE Lleida | 3 | 1 | 0 | 2 | 2:2 | 0 | 2:4 |
| 12 |
|
CD Condal | 3 | 1 | 0 | 2 | 5:6 | -1 | 2:4 |
| 13 |
|
Algeciras CF | 3 | 0 | 2 | 1 | 3:4 | -1 | 2:4 |
| 14 |
|
CD Constància | 3 | 1 | 0 | 2 | 2:3 | -1 | 2:4 |
| 15 |
|
Real Murcia | 3 | 1 | 0 | 2 | 7:6 | 1 | 2:4 |
| 16 |
|
Cádiz CF | 3 | 0 | 1 | 2 | 1:5 | -4 | 1:5 |
