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| 02.10.1966 | CD Logroñés | - | Real Oviedo | 2:0 | ||
| Sporting Gijón | - | CA Osasuna | 4:0 | |||
| Racing Ferrol | - | CF Calvo Sotelo | 2:1 | |||
| Burgos CF | - | CD Tenerife | 2:0 | |||
| Gimnástica Torrelavega | - | Real Valladolid | 1:0 | |||
| SD Indautxu | - | Celta de Vigo | 1:0 | |||
| UP Langreo | - | Racing Santander | 1:2 | |||
| Real Sociedad | - | Rayo Vallecano | 1:0 | |||
| Real Betis | - | CD Mestalla | 5:0 | |||
| UE Lleida | - | CD Condal | 0:0 | |||
| Cádiz CF | - | Recreativo Huelva | 1:1 | |||
| Levante UD | - | RCD Mallorca | 3:0 | |||
| Algeciras CF | - | CA Ceuta | 1:0 | |||
| CD Málaga | - | CD Castellón | 1:0 | |||
| CE Europa | - | CF Badalona | 1:0 | |||
| CD Constància | - | Real Murcia | 0:0 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sporting Gijón | 4 | 3 | 1 | 0 | 8:1 | 7 | 7:1 |
| 2 |
|
Rayo Vallecano | 4 | 3 | 0 | 1 | 11:1 | 10 | 6:2 |
| 3 |
|
Racing Ferrol | 4 | 3 | 0 | 1 | 11:3 | 8 | 6:2 |
| 4 |
|
Racing Santander | 4 | 3 | 0 | 1 | 9:3 | 6 | 6:2 |
| 5 |
|
CF Calvo Sotelo | 4 | 2 | 1 | 1 | 6:2 | 4 | 5:3 |
| 6 |
|
Celta de Vigo | 4 | 2 | 0 | 2 | 6:5 | 1 | 4:4 |
| 7 |
|
UP Langreo | 4 | 2 | 0 | 2 | 4:4 | 0 | 4:4 |
| 8 |
|
Real Sociedad | 4 | 2 | 0 | 2 | 4:7 | -3 | 4:4 |
| 9 |
|
CD Logroñés | 4 | 2 | 0 | 2 | 3:10 | -7 | 4:4 |
| 10 |
|
Real Oviedo | 4 | 2 | 0 | 2 | 5:5 | 0 | 4:4 |
| 11 |
|
Gimnástica Torrelavega | 4 | 2 | 0 | 2 | 5:9 | -4 | 4:4 |
| 12 |
|
SD Indautxu | 4 | 1 | 1 | 2 | 1:5 | -4 | 3:5 |
| 13 |
|
Real Valladolid | 4 | 1 | 0 | 3 | 4:5 | -1 | 2:6 |
| 14 |
|
Burgos CF | 4 | 1 | 0 | 3 | 2:7 | -5 | 2:6 |
| 15 |
|
CA Osasuna | 4 | 1 | 0 | 3 | 5:11 | -6 | 2:6 |
| 16 |
|
CD Tenerife | 4 | 0 | 1 | 3 | 2:8 | -6 | 1:7 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Betis | 4 | 3 | 1 | 0 | 11:2 | 9 | 7:1 |
| 2 |
|
Levante UD | 4 | 3 | 0 | 1 | 6:3 | 3 | 6:2 |
| 3 |
|
CD Málaga | 4 | 2 | 2 | 0 | 4:2 | 2 | 6:2 |
| 4 |
|
Recreativo Huelva | 4 | 2 | 1 | 1 | 4:3 | 1 | 5:3 |
| 5 |
|
CD Castellón | 4 | 2 | 1 | 1 | 3:2 | 1 | 5:3 |
| 6 |
|
CE Europa | 4 | 2 | 1 | 1 | 3:2 | 1 | 5:3 |
| 7 |
|
Algeciras CF | 4 | 1 | 2 | 1 | 4:4 | 0 | 4:4 |
| 8 |
|
UE Lleida | 4 | 1 | 1 | 2 | 2:2 | 0 | 3:5 |
| 9 |
|
CD Condal | 4 | 1 | 1 | 2 | 5:6 | -1 | 3:5 |
| 10 |
|
RCD Mallorca | 4 | 1 | 1 | 2 | 3:4 | -1 | 3:5 |
| 11 |
|
CD Constància | 4 | 1 | 1 | 2 | 2:3 | -1 | 3:5 |
| 12 |
|
CA Ceuta | 4 | 1 | 1 | 2 | 4:6 | -2 | 3:5 |
| 13 |
|
CF Badalona | 4 | 1 | 1 | 2 | 2:4 | -2 | 3:5 |
| 14 |
|
CD Mestalla | 4 | 1 | 1 | 2 | 7:14 | -7 | 3:5 |
| 15 |
|
Real Murcia | 4 | 1 | 1 | 2 | 7:6 | 1 | 3:5 |
| 16 |
|
Cádiz CF | 4 | 0 | 2 | 2 | 2:6 | -4 | 2:6 |
