| 1. Ronde | 14.08.2021 | SD Ponferradina | - | AD Alcorcón | 1:0 | ||||
| 2. Ronde | 21.08.2021 | AD Alcorcón | - | CF Fuenlabrada | 0:2 | ||||
| 3. Ronde | 27.08.2021 | Málaga CF | - | AD Alcorcón | 1:0 |  |
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| 4. Ronde | 05.09.2021 | AD Alcorcón | - | Real Zaragoza | 1:2 | |
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| 5. Ronde | 11.09.2021 | CD Mirandés | - | AD Alcorcón | 1:3 | ||||
| 11. Ronde | 20.10.2021 | AD Alcorcón | - | CD Leganés | 3:3 | ||||
| 12. Ronde | 24.10.2021 | UD Las Palmas | - | AD Alcorcón | 3:0 | ||||
| 13. Ronde | 01.11.2021 | AD Alcorcón | - | UD Ibiza | 0:2 | |
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| 14. Ronde | 04.11.2021 | Girona FC | - | AD Alcorcón | 3:1 | |
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| 15. Ronde | 07.11.2021 | AD Alcorcón | - | SD Amorebieta | 2:2 | ||||
| 16. Ronde | 13.11.2021 | SD Eibar | - | AD Alcorcón | 2:1 | ||||
| 20. Ronde | 12.12.2021 | AD Alcorcón | - | FC Cartagena | 1:1 | |
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| 22. Ronde | 03.01.2022 | AD Alcorcón | - | Málaga CF | 0:1 | ||||
| 23. Ronde | 08.01.2022 | UD Ibiza | - | AD Alcorcón | 6:2 | ||||
| 25. Ronde | 30.01.2022 | CD Leganés | - | AD Alcorcón | 1:0 |
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