| 1. Ronde | 15.08.2021 | FC Barcelona | - | Real Sociedad | 4:2 |  |
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| 2. Ronde | 21.08.2021 | Athletic Club | - | FC Barcelona | 1:1 | ||||
| 3. Ronde | 29.08.2021 | FC Barcelona | - | Getafe CF | 2:1 | |
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| 5. Ronde | 20.09.2021 | FC Barcelona | - | Granada CF | 1:1 | ||||
| 6. Ronde | 23.09.2021 | Cádiz CF | - | FC Barcelona | 0:0 |  |
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| 8. Ronde | 02.10.2021 | Atlético Madrid | - | FC Barcelona | 2:0 | ||||
| 9. Ronde | 17.10.2021 | FC Barcelona | - | Valencia CF | 3:1 | ||||
| 10. Ronde | 24.10.2021 | FC Barcelona | - | Real Madrid | 1:2 | ||||
| 11. Ronde | 27.10.2021 | Rayo Vallecano | - | FC Barcelona | 1:0 |
Spanje
