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| 22.10.2005 | 20:00 | Sevilla FC | - | Deportivo Alavés | 2:0 (1:0) | |
| 22:00 | FC Barcelona | - | CA Osasuna | 3:0 (0:0) | ||
| 23.10.2005 | 17:00 | Villarreal CF | - | RCD Mallorca | 3:0 (3:0) | |
| 17:00 | Cádiz CF | - | Athletic Bilbao | 1:0 (1:0) | ||
| 17:00 | Celta de Vigo | - | Espanyol | 1:0 (0:0) | ||
| 17:00 | Real Sociedad | - | Deportivo La Coruña | 2:0 (0:0) | ||
| 17:00 | Getafe CF | - | Real Zaragoza | 5:2 (4:0) | ||
| 17:00 | Málaga CF | - | Real Betis | 5:0 (2:0) | ||
| 19:00 | Racing Santander | - | Atlético Madrid | 0:1 (0:0) | ||
| 21:00 | Real Madrid | - | Valencia CF | 1:2 (1:2) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Getafe CF | 8 | 5 | 2 | 1 | 16:9 | 7 | 17 |
| 2 |
|
Celta de Vigo | 8 | 5 | 1 | 2 | 11:8 | 3 | 16 |
| 3 |
|
Real Madrid | 8 | 5 | 0 | 3 | 18:8 | 10 | 15 |
| 4 |
|
Valencia CF | 8 | 4 | 3 | 1 | 14:11 | 3 | 15 |
| 5 |
|
CA Osasuna | 8 | 5 | 0 | 3 | 9:8 | 1 | 15 |
| 6 |
|
FC Barcelona | 8 | 3 | 4 | 1 | 17:10 | 7 | 13 |
| 7 |
|
Real Sociedad | 8 | 4 | 1 | 3 | 12:14 | -2 | 13 |
| 8 |
|
Villarreal CF | 8 | 3 | 3 | 2 | 13:9 | 4 | 12 |
| 9 |
|
Cádiz CF | 8 | 3 | 3 | 2 | 7:6 | 1 | 12 |
| 10 |
|
Sevilla FC | 8 | 3 | 3 | 2 | 7:5 | 2 | 12 |
| 11 |
|
Málaga CF | 8 | 3 | 1 | 4 | 13:10 | 3 | 10 |
| 12 |
|
Deportivo La Coruña | 8 | 2 | 4 | 2 | 9:10 | -1 | 10 |
| 13 |
|
Atlético Madrid | 8 | 3 | 1 | 4 | 7:9 | -2 | 10 |
| 14 |
|
Real Betis | 8 | 2 | 3 | 3 | 5:12 | -7 | 9 |
| 15 |
|
Real Zaragoza | 8 | 1 | 5 | 2 | 10:12 | -2 | 8 |
| 16 |
|
Racing Santander | 8 | 2 | 2 | 4 | 3:5 | -2 | 8 |
| 17 |
|
Espanyol | 8 | 2 | 1 | 5 | 5:10 | -5 | 7 |
| 18 |
|
Deportivo Alavés | 8 | 1 | 3 | 4 | 7:13 | -6 | 6 |
| 19 |
|
Athletic Bilbao | 8 | 1 | 2 | 5 | 7:11 | -4 | 5 |
| 20 |
|
RCD Mallorca | 8 | 1 | 2 | 5 | 7:17 | -10 | 5 |
