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| 10.03.2007 | 20:00 | Levante UD | - | Villarreal CF | 0:2 (0:1) | |
| 22:00 | FC Barcelona | - | Real Madrid | 3:3 (2:2) | ||
| 11.03.2007 | 17:00 | Real Sociedad | - | RCD Mallorca | 3:1 (2:1) | |
| 17:00 | Real Betis | - | Real Zaragoza | 1:1 (1:1) | ||
| 17:00 | Getafe CF | - | Recreativo Huelva | 1:1 (1:1) | ||
| 17:00 | Gimnàstic de Tarragona | - | Sevilla FC | 1:0 (0:0) | ||
| 17:00 | Celta de Vigo | - | Athletic Bilbao | 1:1 (1:0) | ||
| 17:00 | Racing Santander | - | Espanyol | 1:1 (1:1) | ||
| 19:00 | Atlético Madrid | - | Deportivo La Coruña | 2:0 (1:0) | ||
| 21:00 | CA Osasuna | - | Valencia CF | 1:1 (1:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sevilla FC | 26 | 15 | 5 | 6 | 46:24 | 22 | 50 |
| 2 |
|
FC Barcelona | 26 | 14 | 8 | 4 | 53:25 | 28 | 50 |
| 3 |
|
Valencia CF | 26 | 14 | 5 | 7 | 37:24 | 13 | 47 |
| 4 |
|
Real Madrid | 26 | 13 | 6 | 7 | 35:24 | 11 | 45 |
| 5 |
|
Real Zaragoza | 26 | 12 | 7 | 7 | 39:27 | 12 | 43 |
| 6 |
|
Atlético Madrid | 26 | 12 | 7 | 7 | 32:22 | 10 | 43 |
| 7 |
|
Recreativo Huelva | 26 | 12 | 5 | 9 | 35:31 | 4 | 41 |
| 8 |
|
Getafe CF | 26 | 10 | 8 | 8 | 23:18 | 5 | 38 |
| 9 |
|
Racing Santander | 26 | 9 | 10 | 7 | 28:30 | -2 | 37 |
| 10 |
|
Espanyol | 26 | 9 | 10 | 7 | 28:27 | 1 | 37 |
| 11 |
|
Villarreal CF | 26 | 10 | 6 | 10 | 25:31 | -6 | 36 |
| 12 |
|
Deportivo La Coruña | 26 | 8 | 9 | 9 | 19:28 | -9 | 33 |
| 13 |
|
CA Osasuna | 26 | 9 | 4 | 13 | 31:33 | -2 | 31 |
| 14 |
|
Real Betis | 26 | 7 | 10 | 9 | 25:29 | -4 | 31 |
| 15 |
|
RCD Mallorca | 26 | 8 | 5 | 13 | 26:39 | -13 | 29 |
| 16 |
|
Celta de Vigo | 26 | 6 | 9 | 11 | 27:36 | -9 | 27 |
| 17 |
|
Levante UD | 26 | 6 | 9 | 11 | 22:36 | -14 | 27 |
| 18 |
|
Athletic Bilbao | 26 | 6 | 8 | 12 | 27:37 | -10 | 26 |
| 19 |
|
Gimnàstic de Tarragona | 26 | 5 | 5 | 16 | 28:48 | -20 | 20 |
| 20 |
|
Real Sociedad | 26 | 3 | 8 | 15 | 18:35 | -17 | 17 |
