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| 12.05.2007 | 20:00 | Real Madrid | - | Espanyol | 4:3 (1:3) | |
| 22:00 | Sevilla FC | - | Recreativo Huelva | 2:1 (1:0) | ||
| 13.05.2007 | 17:00 | Getafe CF | - | Atlético Madrid | 1:4 (1:2) | |
| 17:00 | Gimnàstic de Tarragona | - | Real Sociedad | 1:3 (1:2) | ||
| 17:00 | Celta de Vigo | - | Levante UD | 1:2 (0:1) | ||
| 17:00 | CA Osasuna | - | Villarreal CF | 1:4 (1:1) | ||
| 17:00 | Racing Santander | - | RCD Mallorca | 0:2 (0:0) | ||
| 17:00 | Athletic Bilbao | - | Deportivo La Coruña | 1:1 (0:0) | ||
| 19:00 | FC Barcelona | - | Real Betis | 1:1 (1:0) | ||
| 21:00 | Valencia CF | - | Real Zaragoza | 2:0 (2:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 34 | 20 | 6 | 8 | 55:34 | 21 | 66 |
| 2 |
|
FC Barcelona | 34 | 19 | 9 | 6 | 64:30 | 34 | 66 |
| 3 |
|
Sevilla FC | 34 | 19 | 7 | 8 | 59:32 | 27 | 64 |
| 4 |
|
Valencia CF | 34 | 19 | 5 | 10 | 49:32 | 17 | 62 |
| 5 |
|
Real Zaragoza | 34 | 15 | 10 | 9 | 47:34 | 13 | 55 |
| 6 |
|
Atlético Madrid | 34 | 15 | 9 | 10 | 40:29 | 11 | 54 |
| 7 |
|
Recreativo Huelva | 34 | 14 | 8 | 12 | 46:45 | 1 | 50 |
| 8 |
|
Villarreal CF | 34 | 14 | 8 | 12 | 39:40 | -1 | 50 |
| 9 |
|
Getafe CF | 34 | 13 | 10 | 11 | 33:28 | 5 | 49 |
| 10 |
|
Racing Santander | 34 | 12 | 13 | 9 | 39:41 | -2 | 49 |
| 11 |
|
RCD Mallorca | 34 | 14 | 6 | 14 | 40:42 | -2 | 48 |
| 12 |
|
Espanyol | 34 | 11 | 12 | 11 | 41:43 | -2 | 45 |
| 13 |
|
Deportivo La Coruña | 34 | 11 | 11 | 12 | 25:34 | -9 | 44 |
| 14 |
|
CA Osasuna | 34 | 10 | 7 | 17 | 39:46 | -7 | 37 |
| 15 |
|
Real Betis | 34 | 7 | 15 | 12 | 32:41 | -9 | 36 |
| 16 |
|
Levante UD | 34 | 8 | 12 | 14 | 29:43 | -14 | 36 |
| 17 |
|
Athletic Bilbao | 34 | 8 | 10 | 16 | 37:55 | -18 | 34 |
| 18 |
|
Real Sociedad | 34 | 7 | 9 | 18 | 26:41 | -15 | 30 |
| 19 |
|
Celta de Vigo | 34 | 7 | 9 | 18 | 32:52 | -20 | 30 |
| 20 |
|
Gimnàstic de Tarragona | 34 | 6 | 6 | 22 | 31:61 | -30 | 24 |
