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| 20.10.2007 | 20:00 | Levante UD | - | Sevilla FC | 0:2 (0:2) | |
| 20:00 | Villarreal CF | - | FC Barcelona | 3:1 (3:1) | ||
| 20:00 | Deportivo La Coruña | - | Valencia CF | 2:4 (1:3) | ||
| 22:00 | Espanyol | - | Real Madrid | 2:1 (1:0) | ||
| 21.10.2007 | 17:00 | UD Almería | - | CA Osasuna | 2:0 (0:0) | |
| 17:00 | Real Valladolid | - | Athletic Bilbao | 1:2 (0:2) | ||
| 17:00 | Real Betis | - | Racing Santander | 1:1 (0:0) | ||
| 17:00 | Getafe CF | - | Real Murcia | 2:0 (0:0) | ||
| 17:00 | Recreativo Huelva | - | RCD Mallorca | 0:2 (0:1) | ||
| 21:00 | Atlético Madrid | - | Real Zaragoza | 4:0 (2:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 8 | 6 | 1 | 1 | 17:5 | 12 | 19 |
| 2 |
|
Villarreal CF | 8 | 6 | 0 | 2 | 14:9 | 5 | 18 |
| 3 |
|
Valencia CF | 8 | 6 | 0 | 2 | 14:11 | 3 | 18 |
| 4 |
|
FC Barcelona | 8 | 5 | 2 | 1 | 17:7 | 10 | 17 |
| 5 |
|
Espanyol | 8 | 5 | 1 | 2 | 12:9 | 3 | 16 |
| 6 |
|
RCD Mallorca | 8 | 4 | 2 | 2 | 15:10 | 5 | 14 |
| 7 |
|
Atlético Madrid | 8 | 4 | 2 | 2 | 15:7 | 8 | 14 |
| 8 |
|
Racing Santander | 8 | 3 | 3 | 2 | 6:8 | -2 | 12 |
| 9 |
|
UD Almería | 8 | 3 | 2 | 3 | 10:8 | 2 | 11 |
| 10 |
|
Real Zaragoza | 8 | 3 | 2 | 3 | 11:13 | -2 | 11 |
| 11 |
|
Sevilla FC | 8 | 3 | 1 | 4 | 14:11 | 3 | 10 |
| 12 |
|
CA Osasuna | 8 | 2 | 3 | 3 | 9:10 | -1 | 9 |
| 13 |
|
Real Murcia | 8 | 2 | 3 | 3 | 7:8 | -1 | 9 |
| 14 |
|
Athletic Bilbao | 8 | 2 | 3 | 3 | 7:10 | -3 | 9 |
| 15 |
|
Recreativo Huelva | 8 | 2 | 2 | 4 | 7:12 | -5 | 8 |
| 16 |
|
Deportivo La Coruña | 8 | 2 | 2 | 4 | 6:12 | -6 | 8 |
| 17 |
|
Real Betis | 8 | 1 | 4 | 3 | 8:9 | -1 | 7 |
| 18 |
|
Getafe CF | 8 | 1 | 2 | 5 | 7:13 | -6 | 5 |
| 19 |
|
Real Valladolid | 8 | 1 | 2 | 5 | 9:17 | -8 | 5 |
| 20 |
|
Levante UD | 8 | 0 | 1 | 7 | 3:19 | -16 | 1 |
