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| 03.11.2012 | 16:00 | Málaga CF | - | Rayo Vallecano | 1:2 (0:1) | |
| 18:00 | FC Barcelona | - | Celta de Vigo | 3:1 (2:1) | ||
| 20:00 | Real Madrid | - | Real Zaragoza | 4:0 (2:0) | ||
| 22:00 | Valencia CF | - | Atlético Madrid | 2:0 (1:0) | ||
| 04.11.2012 | 12:00 | Real Sociedad | - | Espanyol | 0:1 (0:0) | |
| 16:00 | Deportivo La Coruña | - | RCD Mallorca | 1:0 (1:0) | ||
| 17:50 | CA Osasuna | - | Real Valladolid | 0:1 (0:0) | ||
| 19:45 | Granada CF | - | Athletic Bilbao | 1:2 (0:2) | ||
| 21:30 | Sevilla FC | - | Levante UD | 0:0 (0:0) | ||
| 05.11.2012 | 21:30 | Getafe CF | - | Real Betis | 2:4 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 10 | 9 | 1 | 0 | 32:12 | 20 | 28 |
| 2 |
|
Atlético Madrid | 10 | 8 | 1 | 1 | 22:11 | 11 | 25 |
| 3 |
|
Real Madrid | 10 | 6 | 2 | 2 | 25:7 | 18 | 20 |
| 4 |
|
Real Betis | 10 | 6 | 1 | 3 | 17:15 | 2 | 19 |
| 5 |
|
Málaga CF | 10 | 5 | 3 | 2 | 14:7 | 7 | 18 |
| 6 |
|
Levante UD | 10 | 5 | 2 | 3 | 12:14 | -2 | 17 |
| 7 |
|
Sevilla FC | 10 | 4 | 3 | 3 | 12:11 | 1 | 15 |
| 8 |
|
Real Valladolid | 10 | 4 | 2 | 4 | 15:11 | 4 | 14 |
| 9 |
|
Valencia CF | 10 | 4 | 2 | 4 | 13:12 | 1 | 14 |
| 10 |
|
Getafe CF | 10 | 4 | 1 | 5 | 12:16 | -4 | 13 |
| 11 |
|
Rayo Vallecano | 10 | 4 | 1 | 5 | 13:23 | -10 | 13 |
| 12 |
|
Real Zaragoza | 10 | 4 | 0 | 6 | 9:15 | -6 | 12 |
| 13 |
|
RCD Mallorca | 10 | 3 | 2 | 5 | 10:15 | -5 | 11 |
| 14 |
|
Athletic Bilbao | 10 | 3 | 2 | 5 | 14:20 | -6 | 11 |
| 15 |
|
Celta de Vigo | 10 | 3 | 1 | 6 | 11:14 | -3 | 10 |
| 16 |
|
Deportivo La Coruña | 10 | 2 | 4 | 4 | 15:20 | -5 | 10 |
| 17 |
|
Real Sociedad | 10 | 3 | 1 | 6 | 10:15 | -5 | 10 |
| 18 |
|
Espanyol | 10 | 2 | 3 | 5 | 12:15 | -3 | 9 |
| 19 |
|
Granada CF | 10 | 2 | 2 | 6 | 9:17 | -8 | 8 |
| 20 |
|
CA Osasuna | 10 | 1 | 2 | 7 | 8:15 | -7 | 5 |
| Champions League | |
| Champions League Kwali. | |
| Europa League | |
| Europa League Kwali. | |
| Europa League Kwali. | |
| Degradatie |
