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| 05.10.2012 | 21:30 | Celta de Vigo | - | Sevilla FC | 2:0 (0:0) | |
| 06.10.2012 | 16:00 | Rayo Vallecano | - | Deportivo La Coruña | 2:1 (2:1) | |
| 18:00 | Real Zaragoza | - | Getafe CF | 0:1 (0:0) | ||
| 20:00 | Real Valladolid | - | Espanyol | 1:1 (0:0) | ||
| 22:00 | Real Betis | - | Real Sociedad | 2:0 (1:0) | ||
| 07.10.2012 | 12:00 | Levante UD | - | Valencia CF | 1:0 (1:0) | |
| 16:00 | RCD Mallorca | - | Granada CF | 1:2 (0:0) | ||
| 18:00 | Athletic Bilbao | - | CA Osasuna | 1:0 (1:0) | ||
| 19:50 | FC Barcelona | - | Real Madrid | 2:2 (1:1) | ||
| 21:30 | Atlético Madrid | - | Málaga CF | 2:1 (1:1) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 7 | 6 | 1 | 0 | 19:7 | 12 | 19 |
| 2 |
|
Atlético Madrid | 7 | 6 | 1 | 0 | 18:8 | 10 | 19 |
| 3 |
|
Málaga CF | 7 | 4 | 2 | 1 | 11:4 | 7 | 14 |
| 4 |
|
Real Betis | 7 | 4 | 0 | 3 | 12:13 | -1 | 12 |
| 5 |
|
Real Madrid | 7 | 3 | 2 | 2 | 14:7 | 7 | 11 |
| 6 |
|
RCD Mallorca | 7 | 3 | 2 | 2 | 8:6 | 2 | 11 |
| 7 |
|
Sevilla FC | 7 | 3 | 2 | 2 | 8:7 | 1 | 11 |
| 8 |
|
Real Valladolid | 7 | 3 | 1 | 3 | 11:7 | 4 | 10 |
| 9 |
|
Getafe CF | 7 | 3 | 1 | 3 | 8:10 | -2 | 10 |
| 10 |
|
Rayo Vallecano | 7 | 3 | 1 | 3 | 9:14 | -5 | 10 |
| 11 |
|
Levante UD | 7 | 3 | 1 | 3 | 8:13 | -5 | 10 |
| 12 |
|
Celta de Vigo | 7 | 3 | 0 | 4 | 9:8 | 1 | 9 |
| 13 |
|
Real Sociedad | 7 | 3 | 0 | 4 | 8:11 | -3 | 9 |
| 14 |
|
Valencia CF | 7 | 2 | 2 | 3 | 8:9 | -1 | 8 |
| 15 |
|
Granada CF | 7 | 2 | 2 | 3 | 6:10 | -4 | 8 |
| 16 |
|
Athletic Bilbao | 7 | 2 | 2 | 3 | 9:14 | -5 | 8 |
| 17 |
|
Real Zaragoza | 7 | 2 | 0 | 5 | 5:9 | -4 | 6 |
| 18 |
|
Deportivo La Coruña | 7 | 1 | 3 | 3 | 9:14 | -5 | 6 |
| 19 |
|
CA Osasuna | 7 | 1 | 1 | 5 | 7:11 | -4 | 4 |
| 20 |
|
Espanyol | 7 | 0 | 2 | 5 | 8:13 | -5 | 2 |
| Champions League | |
| Champions League Kwali. | |
| Europa League | |
| Europa League Kwali. | |
| Europa League Kwali. | |
| Degradatie |
