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| 23.09.2014 | 20:00 | Real Madrid | - | Elche CF | 5:1 (3:1) | |
| 22:00 | Celta de Vigo | - | Deportivo La Coruña | 2:1 (1:0) | ||
| 24.09.2014 | 20:00 | UD Almería | - | Atlético Madrid | 0:1 (0:0) | |
| 20:00 | SD Eibar | - | Villarreal CF | 1:1 (1:0) | ||
| 20:00 | Rayo Vallecano | - | Athletic Bilbao | 2:1 (1:1) | ||
| 22:00 | Sevilla FC | - | Real Sociedad | 1:0 (1:0) | ||
| 22:00 | Granada CF | - | Levante UD | 0:1 (0:0) | ||
| 22:00 | Málaga CF | - | FC Barcelona | 0:0 (0:0) | ||
| 25.09.2014 | 20:00 | Espanyol | - | Getafe CF | 2:0 (0:0) | |
| 22:00 | Valencia CF | - | Córdoba CF | 3:0 (2:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia CF | 5 | 4 | 1 | 0 | 13:2 | 11 | 13 |
| 2 |
|
FC Barcelona | 5 | 4 | 1 | 0 | 11:0 | 11 | 13 |
| 3 |
|
Sevilla FC | 5 | 4 | 1 | 0 | 9:3 | 6 | 13 |
| 4 |
|
Atlético Madrid | 5 | 3 | 2 | 0 | 7:4 | 3 | 11 |
| 5 |
|
Real Madrid | 5 | 3 | 0 | 2 | 18:9 | 9 | 9 |
| 6 |
|
Celta de Vigo | 5 | 2 | 3 | 0 | 10:7 | 3 | 9 |
| 7 |
|
Villarreal CF | 5 | 2 | 2 | 1 | 7:4 | 3 | 8 |
| 8 |
|
Granada CF | 5 | 2 | 2 | 1 | 4:3 | 1 | 8 |
| 9 |
|
SD Eibar | 5 | 2 | 1 | 2 | 5:4 | 1 | 7 |
| 10 |
|
Málaga CF | 5 | 1 | 3 | 1 | 3:5 | -2 | 6 |
| 11 |
|
Espanyol | 5 | 1 | 2 | 2 | 7:8 | -1 | 5 |
| 12 |
|
UD Almería | 5 | 1 | 2 | 2 | 4:5 | -1 | 5 |
| 13 |
|
Rayo Vallecano | 5 | 1 | 2 | 2 | 8:10 | -2 | 5 |
| 14 |
|
Real Sociedad | 5 | 1 | 1 | 3 | 7:8 | -1 | 4 |
| 15 |
|
Elche CF | 5 | 1 | 1 | 3 | 5:13 | -8 | 4 |
| 16 |
|
Levante UD | 5 | 1 | 1 | 3 | 1:10 | -9 | 4 |
| 17 |
|
Deportivo La Coruña | 5 | 1 | 1 | 3 | 7:14 | -7 | 4 |
| 18 |
|
Athletic Bilbao | 5 | 1 | 0 | 4 | 4:6 | -2 | 3 |
| 19 |
|
Getafe CF | 5 | 1 | 0 | 4 | 2:10 | -8 | 3 |
| 20 |
|
Córdoba CF | 5 | 0 | 2 | 3 | 3:10 | -7 | 2 |
| Champions League | |
| Champions League Kwali. | |
| Europa League | |
| Europa League Kwali. | |
| Degradatie |
