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| 05.11.2021 | 21:00 | Athletic Bilbao | - | Cádiz CF | 0:1 (0:1) | |
| 06.11.2021 | 14:00 | Espanyol | - | Granada CF | 2:0 (2:0) | |
| 16:15 | Celta de Vigo | - | FC Barcelona | 3:3 (0:3) | ||
| 18:30 | Deportivo Alavés | - | Levante UD | 2:1 (0:1) | ||
| 21:00 | Real Madrid | - | Rayo Vallecano | 2:1 (2:0) | ||
| 07.11.2021 | 14:00 | Villarreal CF | - | Getafe CF | 1:0 (1:0) | |
| 16:15 | Valencia CF | - | Atlético Madrid | 3:3 (0:1) | ||
| 18:30 | CA Osasuna | - | Real Sociedad | 0:2 (0:0) | ||
| 18:30 | RCD Mallorca | - | Elche CF | 2:2 (0:0) | ||
| 21:00 | Real Betis | - | Sevilla FC | 0:2 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 13 | 9 | 3 | 1 | 29:13 | 16 | 30 |
| 2 |
|
Sevilla FC | 13 | 8 | 4 | 1 | 22:8 | 14 | 28 |
| 3 |
|
Real Sociedad | 13 | 8 | 4 | 1 | 19:10 | 9 | 28 |
| 4 |
|
Atlético Madrid | 13 | 6 | 5 | 2 | 22:15 | 7 | 23 |
| 5 |
|
Real Betis | 13 | 6 | 3 | 4 | 19:17 | 2 | 21 |
| 6 |
|
Rayo Vallecano | 13 | 6 | 2 | 5 | 19:14 | 5 | 20 |
| 7 |
|
CA Osasuna | 13 | 5 | 4 | 4 | 14:17 | -3 | 19 |
| 8 |
|
FC Barcelona | 13 | 4 | 6 | 3 | 20:16 | 4 | 18 |
| 9 |
|
Athletic Bilbao | 13 | 4 | 6 | 3 | 11:9 | 2 | 18 |
| 10 |
|
Villarreal CF | 13 | 4 | 6 | 3 | 19:14 | 5 | 18 |
| 11 |
|
Valencia CF | 13 | 4 | 5 | 4 | 21:20 | 1 | 17 |
| 12 |
|
Espanyol | 13 | 4 | 5 | 4 | 14:13 | 1 | 17 |
| 13 |
|
RCD Mallorca | 13 | 3 | 6 | 4 | 13:19 | -6 | 15 |
| 14 |
|
Granada CF | 13 | 3 | 5 | 5 | 13:17 | -4 | 14 |
| 15 |
|
Deportivo Alavés | 13 | 4 | 1 | 8 | 10:20 | -10 | 13 |
| 16 |
|
Celta de Vigo | 13 | 3 | 3 | 7 | 13:17 | -4 | 12 |
| 17 |
|
Cádiz CF | 13 | 2 | 6 | 5 | 12:19 | -7 | 12 |
| 18 |
|
Elche CF | 13 | 2 | 5 | 6 | 11:17 | -6 | 11 |
| 19 |
|
Levante UD | 13 | 0 | 6 | 7 | 12:25 | -13 | 6 |
| 20 |
|
Getafe CF | 13 | 1 | 3 | 9 | 6:19 | -13 | 6 |
| Champions League | |
| Europa League | |
| Degradatie |
