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| 11.03.2022 | 21:00 | Atlético Madrid | - | Cádiz CF | 2:1 (1:1) | |
| 12.03.2022 | 14:00 | Levante UD | - | Espanyol | 1:1 (0:0) | |
| 16:15 | Granada CF | - | Elche CF | 0:1 (0:1) | ||
| 18:30 | Villarreal CF | - | Celta de Vigo | 1:0 (0:0) | ||
| 21:00 | Getafe CF | - | Valencia CF | 0:0 (0:0) | ||
| 13.03.2022 | 14:00 | Rayo Vallecano | - | Sevilla FC | 1:1 (0:0) | |
| 16:15 | Real Betis | - | Athletic Bilbao | 1:0 (1:0) | ||
| 18:30 | Real Sociedad | - | Deportivo Alavés | 1:0 (0:0) | ||
| 21:00 | FC Barcelona | - | CA Osasuna | 4:0 (3:0) | ||
| 14.03.2022 | 21:00 | RCD Mallorca | - | Real Madrid | 0:3 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 28 | 20 | 6 | 2 | 59:21 | 38 | 66 |
| 2 |
|
Sevilla FC | 28 | 15 | 11 | 2 | 40:19 | 21 | 56 |
| 3 |
|
FC Barcelona | 28 | 14 | 9 | 5 | 52:30 | 22 | 51 |
| 4 |
|
Atlético Madrid | 28 | 15 | 6 | 7 | 52:36 | 16 | 51 |
| 5 |
|
Real Betis | 28 | 15 | 4 | 9 | 50:35 | 15 | 49 |
| 6 |
|
Real Sociedad | 28 | 13 | 8 | 7 | 29:29 | 0 | 47 |
| 7 |
|
Villarreal CF | 28 | 12 | 9 | 7 | 48:26 | 22 | 45 |
| 8 |
|
Athletic Bilbao | 28 | 10 | 10 | 8 | 32:27 | 5 | 40 |
| 9 |
|
Valencia CF | 28 | 9 | 10 | 9 | 41:43 | -2 | 37 |
| 10 |
|
Celta de Vigo | 28 | 9 | 8 | 11 | 33:32 | 1 | 35 |
| 11 |
|
Rayo Vallecano | 28 | 10 | 5 | 13 | 30:33 | -3 | 35 |
| 12 |
|
CA Osasuna | 28 | 9 | 8 | 11 | 26:35 | -9 | 35 |
| 13 |
|
Espanyol | 28 | 8 | 9 | 11 | 34:41 | -7 | 33 |
| 14 |
|
Elche CF | 28 | 8 | 8 | 12 | 30:39 | -9 | 32 |
| 15 |
|
Getafe CF | 28 | 6 | 10 | 12 | 26:32 | -6 | 28 |
| 16 |
|
RCD Mallorca | 28 | 6 | 8 | 14 | 26:48 | -22 | 26 |
| 17 |
|
Granada CF | 28 | 5 | 10 | 13 | 28:44 | -16 | 25 |
| 18 |
|
Cádiz CF | 28 | 4 | 12 | 12 | 24:41 | -17 | 24 |
| 19 |
|
Deportivo Alavés | 28 | 5 | 7 | 16 | 21:45 | -24 | 22 |
| 20 |
|
Levante UD | 28 | 3 | 10 | 15 | 30:55 | -25 | 19 |
| Champions League | |
| Europa League | |
| Degradatie |
