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| 25.09.2021 | 14:00 | Deportivo Alavés | - | Atlético Madrid | 1:0 (1:0) | |
| 16:15 | Valencia CF | - | Athletic Bilbao | 1:1 (0:0) | ||
| 18:30 | Sevilla FC | - | Espanyol | 2:0 (1:0) | ||
| 21:00 | Real Madrid | - | Villarreal CF | 0:0 (0:0) | ||
| 26.09.2021 | 14:00 | RCD Mallorca | - | CA Osasuna | 2:3 (2:1) | |
| 16:15 | FC Barcelona | - | Levante UD | 3:0 (2:0) | ||
| 18:30 | Rayo Vallecano | - | Cádiz CF | 3:1 (2:1) | ||
| 18:30 | Real Sociedad | - | Elche CF | 1:0 (0:0) | ||
| 21:00 | Real Betis | - | Getafe CF | 2:0 (1:0) | ||
| 27.09.2021 | 21:00 | Celta de Vigo | - | Granada CF | 1:0 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 7 | 5 | 2 | 0 | 21:8 | 13 | 17 |
| 2 |
|
Real Sociedad | 7 | 5 | 1 | 1 | 10:6 | 4 | 16 |
| 3 |
|
Sevilla FC | 7 | 4 | 3 | 0 | 11:3 | 8 | 15 |
| 4 |
|
Atlético Madrid | 7 | 4 | 2 | 1 | 9:6 | 3 | 14 |
| 5 |
|
Rayo Vallecano | 7 | 4 | 1 | 2 | 13:7 | 6 | 13 |
| 6 |
|
FC Barcelona | 7 | 3 | 4 | 0 | 12:6 | 6 | 13 |
| 7 |
|
Real Betis | 7 | 3 | 3 | 1 | 11:7 | 4 | 12 |
| 8 |
|
Valencia CF | 7 | 3 | 2 | 2 | 12:8 | 4 | 11 |
| 9 |
|
CA Osasuna | 7 | 3 | 2 | 2 | 10:11 | -1 | 11 |
| 10 |
|
Villarreal CF | 7 | 2 | 5 | 0 | 11:5 | 6 | 11 |
| 11 |
|
Athletic Bilbao | 7 | 2 | 4 | 1 | 6:4 | 2 | 10 |
| 12 |
|
RCD Mallorca | 7 | 2 | 2 | 3 | 6:12 | -6 | 8 |
| 13 |
|
Celta de Vigo | 7 | 2 | 1 | 4 | 7:10 | -3 | 7 |
| 14 |
|
Elche CF | 7 | 1 | 3 | 3 | 4:8 | -4 | 6 |
| 15 |
|
Espanyol | 7 | 1 | 3 | 3 | 4:7 | -3 | 6 |
| 16 |
|
Cádiz CF | 7 | 1 | 3 | 3 | 7:11 | -4 | 6 |
| 17 |
|
Levante UD | 7 | 0 | 4 | 3 | 6:12 | -6 | 4 |
| 18 |
|
Granada CF | 7 | 0 | 3 | 4 | 5:12 | -7 | 3 |
| 19 |
|
Deportivo Alavés | 7 | 1 | 0 | 6 | 4:16 | -12 | 3 |
| 20 |
|
Getafe CF | 7 | 0 | 0 | 7 | 2:12 | -10 | 0 |
| Champions League | |
| Europa League | |
| Degradatie |
