| 1. Ronde | 14.08.2022 | SC Freiburg [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 2:0 | ||||
| 2. Ronde | 20.08.2022 | 1. FSV Mainz 05 [B-jun] | - | SpVgg Unterhaching [B-jun] | 1:0 | ||||
| 6. Ronde | 18.09.2022 | 1. FC Saarbrücken [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 0:5 | ||||
| 7. Ronde | 02.10.2022 | 1. FSV Mainz 05 [B-jun] | - | FC Augsburg [B-jun] | 3:2 | ||||
| 8. Ronde | 09.10.2022 | Karlsruher SC [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 0:0 | ||||
| 9. Ronde | 29.10.2022 | 1. FSV Mainz 05 [B-jun] | - | 1. FC Nürnberg [B-jun] | 5:1 | ||||
| 10. Ronde | 05.11.2022 | Eintracht Frankfurt [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 4:2 | ||||
| 11. Ronde | 12.11.2022 | 1. FSV Mainz 05 [B-jun] | - | Jahn Regensburg [B-jun] | 0:2 | ||||
| 12. Ronde | 20.11.2022 | SpVgg Greuther Fürth [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 1:2 | ||||
| 14. Ronde | 11.12.2022 | VfB Stuttgart [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 1:1 | ||||
| 15. Ronde | 26.02.2023 | 1. FSV Mainz 05 [B-jun] | - | TSV 1860 München [B-jun] | 0:3 | ||||
| 16. Ronde | 04.03.2023 | Bayern München [B-jun] | - | 1. FSV Mainz 05 [B-jun] | 0:3 |  |
Duitsland