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| 21.10.2006 | 20:00 | Villarreal CF | - | Levante UD | 1:1 (0:0) | |
| 20:00 | Real Zaragoza | - | Real Betis | 2:1 (2:0) | ||
| 22:00 | Deportivo La Coruña | - | Atlético Madrid | 1:0 (0:0) | ||
| 22.10.2006 | 17:00 | RCD Mallorca | - | Real Sociedad | 0:0 (0:0) | |
| 17:00 | Recreativo Huelva | - | Getafe CF | 1:2 (0:1) | ||
| 17:00 | Sevilla FC | - | Gimnàstic de Tarragona | 2:1 (2:0) | ||
| 17:00 | Athletic Bilbao | - | Celta de Vigo | 0:1 (0:1) | ||
| 17:00 | Valencia CF | - | CA Osasuna | 1:0 (1:0) | ||
| 17:00 | Espanyol | - | Racing Santander | 2:2 (1:1) | ||
| 21:00 | Real Madrid | - | FC Barcelona | 2:0 (1:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia CF | 7 | 5 | 1 | 1 | 13:5 | 8 | 16 |
| 2 |
|
FC Barcelona | 7 | 5 | 1 | 1 | 16:7 | 9 | 16 |
| 3 |
|
Sevilla FC | 7 | 5 | 0 | 2 | 15:9 | 6 | 15 |
| 4 |
|
Deportivo La Coruña | 7 | 4 | 2 | 1 | 9:5 | 4 | 14 |
| 5 |
|
Real Madrid | 7 | 4 | 2 | 1 | 10:3 | 7 | 14 |
| 6 |
|
Real Zaragoza | 7 | 4 | 1 | 2 | 16:10 | 6 | 13 |
| 7 |
|
Atlético Madrid | 7 | 4 | 1 | 2 | 10:6 | 4 | 13 |
| 8 |
|
Getafe CF | 7 | 4 | 1 | 2 | 6:4 | 2 | 13 |
| 9 |
|
Recreativo Huelva | 7 | 3 | 1 | 3 | 9:8 | 1 | 10 |
| 10 |
|
Celta de Vigo | 7 | 3 | 1 | 3 | 10:11 | -1 | 10 |
| 11 |
|
Villarreal CF | 7 | 2 | 3 | 2 | 6:7 | -1 | 9 |
| 12 |
|
RCD Mallorca | 7 | 2 | 3 | 2 | 4:5 | -1 | 9 |
| 13 |
|
Levante UD | 7 | 2 | 2 | 3 | 7:12 | -5 | 8 |
| 14 |
|
CA Osasuna | 7 | 2 | 1 | 4 | 4:7 | -3 | 7 |
| 15 |
|
Racing Santander | 7 | 1 | 3 | 3 | 6:10 | -4 | 6 |
| 16 |
|
Espanyol | 7 | 1 | 3 | 3 | 4:8 | -4 | 6 |
| 17 |
|
Athletic Bilbao | 7 | 1 | 2 | 4 | 6:14 | -8 | 5 |
| 18 |
|
Real Betis | 7 | 1 | 1 | 5 | 8:11 | -3 | 4 |
| 19 |
|
Gimnàstic de Tarragona | 7 | 1 | 1 | 5 | 7:15 | -8 | 4 |
| 20 |
|
Real Sociedad | 7 | 0 | 2 | 5 | 5:14 | -9 | 2 |
