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| 28.10.2006 | 20:00 | FC Barcelona | - | Recreativo Huelva | 3:0 (1:0) | |
| 20:00 | Racing Santander | - | Valencia CF | 1:0 (0:0) | ||
| 22:00 | Gimnàstic de Tarragona | - | Real Madrid | 1:3 (1:1) | ||
| 29.10.2006 | 17:00 | Levante UD | - | Espanyol | 0:0 (0:0) | |
| 17:00 | Real Sociedad | - | Villarreal CF | 0:1 (0:0) | ||
| 17:00 | Real Betis | - | RCD Mallorca | 0:1 (0:0) | ||
| 17:00 | Getafe CF | - | Deportivo La Coruña | 2:0 (1:0) | ||
| 17:00 | Celta de Vigo | - | Sevilla FC | 1:2 (1:1) | ||
| 19:00 | CA Osasuna | - | Athletic Bilbao | 1:1 (0:1) | ||
| 21:00 | Atlético Madrid | - | Real Zaragoza | 0:1 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 8 | 6 | 1 | 1 | 19:7 | 12 | 19 |
| 2 |
|
Sevilla FC | 8 | 6 | 0 | 2 | 17:10 | 7 | 18 |
| 3 |
|
Real Madrid | 8 | 5 | 2 | 1 | 13:4 | 9 | 17 |
| 4 |
|
Real Zaragoza | 8 | 5 | 1 | 2 | 17:10 | 7 | 16 |
| 5 |
|
Valencia CF | 8 | 5 | 1 | 2 | 13:6 | 7 | 16 |
| 6 |
|
Getafe CF | 8 | 5 | 1 | 2 | 8:4 | 4 | 16 |
| 7 |
|
Deportivo La Coruña | 8 | 4 | 2 | 2 | 9:7 | 2 | 14 |
| 8 |
|
Atlético Madrid | 8 | 4 | 1 | 3 | 10:7 | 3 | 13 |
| 9 |
|
Villarreal CF | 8 | 3 | 3 | 2 | 7:7 | 0 | 12 |
| 10 |
|
RCD Mallorca | 8 | 3 | 3 | 2 | 5:5 | 0 | 12 |
| 11 |
|
Celta de Vigo | 8 | 3 | 1 | 4 | 11:13 | -2 | 10 |
| 12 |
|
Recreativo Huelva | 8 | 3 | 1 | 4 | 9:11 | -2 | 10 |
| 13 |
|
Racing Santander | 8 | 2 | 3 | 3 | 7:10 | -3 | 9 |
| 14 |
|
Levante UD | 8 | 2 | 3 | 3 | 7:12 | -5 | 9 |
| 15 |
|
CA Osasuna | 8 | 2 | 2 | 4 | 5:8 | -3 | 8 |
| 16 |
|
Espanyol | 8 | 1 | 4 | 3 | 4:8 | -4 | 7 |
| 17 |
|
Athletic Bilbao | 8 | 1 | 3 | 4 | 7:15 | -8 | 6 |
| 18 |
|
Real Betis | 8 | 1 | 1 | 6 | 8:12 | -4 | 4 |
| 19 |
|
Gimnàstic de Tarragona | 8 | 1 | 1 | 6 | 8:18 | -10 | 4 |
| 20 |
|
Real Sociedad | 8 | 0 | 2 | 6 | 5:15 | -10 | 2 |
