| 6. Ronde | 26.09.2021 | SSC Napoli | - | Cagliari Calcio | 2:0 | ||||
| 7. Ronde | 03.10.2021 | ACF Fiorentina | - | SSC Napoli | 1:2 |  |
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| 10. Ronde | 28.10.2021 | SSC Napoli | - | Bologna FC | 3:0 | ||||
| 14. Ronde | 28.11.2021 | SSC Napoli | - | Lazio | 4:0 | |
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| 15. Ronde | 01.12.2021 | Sassuolo Calcio | - | SSC Napoli | 2:2 | |
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| 16. Ronde | 04.12.2021 | SSC Napoli | - | Atalanta | 2:3 | ||||
| 17. Ronde | 12.12.2021 | SSC Napoli | - | Empoli FC | 0:1 | ||||
| 18. Ronde | 19.12.2021 | AC Milan | - | SSC Napoli | 0:1 | ||||
| 19. Ronde | 22.12.2021 | SSC Napoli | - | Spezia Calcio | 0:1 | ||||
| 20. Ronde | 06.01.2022 | Juventus | - | SSC Napoli | 1:1 | |
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| 21. Ronde | 09.01.2022 | SSC Napoli | - | Sampdoria | 1:0 | ||||
| 22. Ronde | 17.01.2022 | Bologna FC | - | SSC Napoli | 0:2 | ||||
| 26. Ronde | 21.02.2022 | Cagliari Calcio | - | SSC Napoli | 1:1 | ||||
| 27. Ronde | 27.02.2022 | Lazio | - | SSC Napoli | 1:2 | ||||
| 32. Ronde | 10.04.2022 | SSC Napoli | - | ACF Fiorentina | 2:3 | ||||
| 33. Ronde | 18.04.2022 | SSC Napoli | - | AS Roma | 1:1 | ||||
| 35. Ronde | 30.04.2022 | SSC Napoli | - | Sassuolo Calcio | 6:1 | ||||
| 37. Ronde | 15.05.2022 | SSC Napoli | - | Genoa CFC | 3:0 | ||||
| 38. Ronde | 22.05.2022 | Spezia Calcio | - | SSC Napoli | 0:3 |  |
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