| 3. Ronde | 27.09.2020 | FC Barcelona | - | Villarreal CF | 4:0 | ||||
| 4. Ronde | 01.10.2020 | Celta de Vigo | - | FC Barcelona | 0:3 |  |
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| 5. Ronde | 04.10.2020 | FC Barcelona | - | Sevilla FC | 1:1 | ||||
| 6. Ronde | 17.10.2020 | Getafe CF | - | FC Barcelona | 1:0 |  |
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| 8. Ronde | 31.10.2020 | Deportivo Alavés | - | FC Barcelona | 1:1 | ||||
| 9. Ronde | 07.11.2020 | FC Barcelona | - | Real Betis | 5:2 | ||||
| 10. Ronde | 21.11.2020 | Atlético Madrid | - | FC Barcelona | 1:0 | ||||
| 21. Ronde | 31.01.2021 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 30. Ronde | 10.04.2021 | Real Madrid | - | FC Barcelona | 2:1 | ||||
| 31. Ronde | 22.04.2021 | FC Barcelona | - | Getafe CF | 5:2 | ||||
| 32. Ronde | 25.04.2021 | Villarreal CF | - | FC Barcelona | 1:2 | ||||
| 33. Ronde | 29.04.2021 | FC Barcelona | - | Granada CF | 1:2 | ||||
| 34. Ronde | 02.05.2021 | Valencia CF | - | FC Barcelona | 2:3 | ||||
| 35. Ronde | 08.05.2021 | FC Barcelona | - | Atlético Madrid | 0:0 | ||||
| 36. Ronde | 11.05.2021 | Levante UD | - | FC Barcelona | 3:3 |
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