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| U | Rapid Bucureşti | - | Hamburger SV | 2:0 (1:0) | ||
| R | Hamburger SV | - | Rapid Bucureşti | 3:1 (2:0) | ||
| U: 09.03.2006 16:00 | R: 15.03.2006 19:00 | Winnaars: Rapid Bucureşti | ||||
| U | FCSB | - | Real Betis | 0:0 (0:0) | ||
| R | Real Betis | - | FCSB | 0:3 (0:0) | ||
| U: 09.03.2006 18:00 | R: 16.03.2006 21:30 | Winnaars: FCSB | ||||
| U | US Palermo | - | FC Schalke 04 | 1:0 (1:0) | ||
| R | FC Schalke 04 | - | US Palermo | 3:0 (1:0) | ||
| U: 09.03.2006 18:00 | R: 16.03.2006 20:30 | Winnaars: FC Schalke 04 | ||||
| U | Lille OSC | - | Sevilla FC | 1:0 (1:0) | ||
| R | Sevilla FC | - | Lille OSC | 2:0 (2:0) | ||
| U: 09.03.2006 19:00 | R: 15.03.2006 21:00 | Winnaars: Sevilla FC | ||||
| U | FC Basel | - | RC Strasbourg | 2:0 (1:0) | ||
| R | RC Strasbourg | - | FC Basel | 2:2 (1:2) | ||
| U: 09.03.2006 20:15 | R: 16.03.2006 18:00 | Winnaars: FC Basel | ||||
| U | Olympique Marseille | - | Zenit St. Petersburg | 0:1 (0:0) | ||
| R | Zenit St. Petersburg | - | Olympique Marseille | 1:1 (0:0) | ||
| U: 09.03.2006 20:45 | R: 16.03.2006 17:00 | Winnaars: Zenit St. Petersburg | ||||
| U | Udinese Calcio | - | Levski Sofia | 0:0 (0:0) | ||
| R | Levski Sofia | - | Udinese Calcio | 2:1 (0:1) | ||
| U: 09.03.2006 20:45 | R: 16.03.2006 17:30 | Winnaars: Levski Sofia | ||||
| U | Middlesbrough FC | - | AS Roma | 1:0 (1:0) | ||
| R | AS Roma | - | Middlesbrough FC | 2:1 (1:1) | ||
| U: 09.03.2006 21:00 | R: 15.03.2006 21:00 | Winnaars: Middlesbrough FC | ||||
